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Germanium diodes

A project log for Clockwork germanium

A retro version of Yet Another (Discrete) Clock, with vintage parts

Yann Guidon / YGDESYann Guidon / YGDES 04/07/2016 at 01:5012 Comments

In the pursuit of authenticity, germanium diodes are being ordered, examined and used.

I already have some 1N60 from a Chinese eBay seller, just in cases I needed to do some fine signal detection (and to change from the Schottky)

Their forward drop tensions (in mV): 284, 281, 283, 281, 279, 280, 278, 282, 279, 280, 281.... pretty good.

What about the reverse leakage ? Voltages are measured across a 10K Ohm resistor when 9.82V is applied to the diode and resistor : 100µV/10K=10nA (my DMM can't resolve more and the readings decrease quickly)


But the "look" of the 1N60 makes it too close to a vulgar 1N4148... Why make a special circuit if it doesn't look special ? So I got myself a little lot of Д9Б (pronounce D9B because it's russian) and their larger glass package lets you see the spring-y point-contact structure. Awesome :-)

I measured the following forward drop voltages (in mV) : 278 286 271 288 255 264... It's less consistent, more scattered, I should expect from 0.2 to 0.3V of drop (this depends of course on the current).

What about the reverse leakage ? Across the 10K resistor I read (in mV): 23, 30, 28, 53, 34, 50, 29, 24, 36, 34... So I have to expect up to 0.5µA of leakage (at 9V). That's 2 orders of magnitude leakier than the 1N60 but still way less than a Germanium transistor...


But wait, the pursuit does not stop there. On the Internet, there is a smal (monetary) line between funky and spooky. I got some crazy looking OA7 diodes and the untrained eye wouldn't know what this 2-legged thing is. "Is this an antique capacitor ?" Awesome ;-)

I got 10pc OA7 (yet). Don't they look cute ? Like they are sleeping in a very wide bed...

I measured the whole lot's characteristics:

drop (mV)Leakage (µA)
12421.6
22451.31
32362.09
42341.61
52371.60
62401.63
72431.30
82381.16
92441.34
102322.27

The drop is lower than the others. This is balanced by a higher leakage, up to 5× the D9B. This is yet a, probably, a better detection diode.

I have once found Philips-made diodes with ultra-low forward-drop voltage for analog detection purposes but they are too modern ;-)


I also found in my archive 40 tiny bead-like diodes. They are pretty and quite unique so they might be used as well, despite being Silicon-based ;-)


More diodes should arrive (D311, more OA7, maybe OA9) and they will be tested as well but there is something else I have to do !

I had bought the first Ge transistors lots because I want(ed) to use them as double diodes... There would be less wiring to do when I want to reset 2 flip-flops with the same signal. So let's see if this works.

I got some МП13Б (MP13B) :

Vf1 (mV)Vf2 (mV)
1186196
2202189
3194201
4206196
5203192
6203191
7202190

(I didn't care about collector/emitter order but they can be guessed by whichever is higher by 10mV)

and МП26А (MP26A):

Vf1 (mV)Vf2 (mV)
1180170
2193180
3194185
4187177
5185174
6190179
7189177

The values are pretty consistent and even lower than the above diodes !

Now it has to be seen if the leakage and the transistor effect will wreak havoc in the circuits...


LEDs are diodes, right ? Alexander just used some for his NAND logic gate. Well I got some AL102BM as well, for function AND aesthetic :-)

The package came with a little datasheet :

It's not very bright but that was the intention, I was looking at the glow of. the first, low-efficieny LEDs. I'm not sure if it's the BM or БМ version, so I can't be sure it's limited to 10mA, if my guesses are good. Well there isn't much light anyway at 10mA or 20mA and it's intended only as small indicator.

This is the best I could do :

Let's hope it's enough ! If I limit the current to 10mA per LED, the display alone will draw 60mA...

Just for the sake of it, I tried to capture the glow of the LED crystal, at very low voltage (otherwise the camera's sensor is flooded and bleeds) :

Can you see the little square ? :-)

Discussions

add_ocean wrote 09/26/2017 at 22:31 point

And, very small amendment :)

using base-emitter junction as a diode must be done with great care, as:

1) it is actually zener with somewhat 6 volts breakdown,

2) it has roughly 10 times more reverse current than base-collector junction.

Д311 has 160 mV forward drop under 1 mA, probably the best we can find,

Д310 is same good and allows up 500 mA (at a price of 10 times more capacitance)

When we need high drop Ge, Д18 or Д20 forward drop is 350 mV under 1 mA.

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Yann Guidon / YGDES wrote 09/26/2017 at 23:04 point

Wow ! thanks !

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add_ocean wrote 09/27/2017 at 09:48 point

Besides. while i value modern LEDs very much for brightness, effectiveness and colors, those АЛ102 are aestetical, as you said. Yes dim, but glowing dice inside silverish can under clear glass window makes style :)

Though old Western devices (Monsanto etc.) are true aestetics too.

Similar visual effect can be seen with modern high power color emitters (Luxeon, etc.), when driving with tiny current. While this is not endorsed by vendors, they can be used as glow dice with current of hundred(s) or even tenths (!) of microamps.

Looking really cool in this role, as their dice is huge!

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Yann Guidon / YGDES wrote 09/27/2017 at 21:59 point

I agree, I've had my share of Luxeons, a decade ago :-D

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SHAOS wrote 04/07/2016 at 16:36 point

yes, right - a little label :)

so, on the 1st page it is saying that it's single indicators AL102AM-AL102DM under standard GOST 1163084 and technical conditions 0.336.041 TU

then diagram with holes etc

then info about weight - 0.45 gram

then information about gold and silver content (0.0000647 gram and 0.0002481 gram respectively per 1000 indicators)

2n page - main electrical parameters for temperature +25+-10 Celsius degree:
1st column - indicator type
2nd column - luminance (not less than, microg?)
3rd column - constant forward voltage (not more than, V)
4th column - measurement mode - constant forward current (mA)

then some info about labeling (note 1): AL102AM - one red dot, AL102BM - two red dots, AL102VM - one green dot, AL102GM - three red dots, AL102DM - two green dots

then info about color of light (note 2): AL102AM/BM/GM - red light, AL102VM/AL102DM - green light

and then OTK stamp (quality control)

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Yann Guidon / YGDES wrote 04/07/2016 at 16:43 point

OOOhhhh this totally makes sense now ! I didn't understand that they mixed red and green data on the same datasheet... I was curious about why the current rating would fall and rise again :-D

And the gold/silver contents part is totally new for me...

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SHAOS wrote 04/07/2016 at 16:51 point

added some minor clarifications

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Yann Guidon / YGDES wrote 04/07/2016 at 17:03 point

It's still unclear to me what the "maximum ratings" are, or what the table explains : is it only the testing parameters that were used for binning ? I don't want to exceed the parameters and break one (I have found one that doesn't work already yet have not tested 10 parts yet).

Edit: ah, it's a mix... "no more than 2.8V"

First photons are emitted around 1.7V.

2.8V couldn't be a testing voltage because red LED are usually much lower than that.

I'm still not sure yet about the AM/BM/VM classification, either. AM is tested at lower current and has lower light, so it's not possible to know which class is "better".

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SHAOS wrote 04/07/2016 at 17:12 point

more dots = better, no?

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Yann Guidon / YGDES wrote 04/07/2016 at 16:34 point

OOOops Alexander is right, it's Д9Б and not Д9B, fixed :-)

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SHAOS wrote 04/07/2016 at 13:30 point

OOO - ЭТИКЕТКА :)

Russians called that way paper 1-pagers (little datasheets) and it literally means "a label" :)

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Yann Guidon / YGDES wrote 04/07/2016 at 16:21 point

I figured this easily because it sounds like the french "étiquette", just with the diminutive suffix "ka"... little étiquette, how cute :-)

Now I'd like to be sure of the meaning of  the other terms, if you could help translate :-)

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