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You'll need to think beyond Joule thief as it isn't practical for that kind of wattage nor that voltage.
I am working on my project, but don't think it would deliver 4W. I am guessing 0.5W (or may be a bit higher) might be a realistic number. I don't have the answer until I try. 0.5V is not an easy voltage to work with as most common parts do not work on that natively.
https://hackaday.io/project/158839-boost-converter-for-low-voltage
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I agree with Marian (above). Resistance of coin cells is something integral to several circuits.
Also, the Tindie price is quite high for such a simple board.
I think you just invented a pretty interesting connector in there...
Now make the output voltage adjustable and add an adjustable series resistance, and this would be really helpful in development.
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I know only one chip http://www.analog.com/en/products/power-management/energy-harvesting/ltc3105.html#product-overview
0.5V is very low for everything